Download C-H Bond Activation and Catalytic Functionalization I by Pierre H. Dixneuf, Henri Doucet PDF

By Pierre H. Dixneuf, Henri Doucet

The sequence themes in Organometallic Chemistry provides severe overviews of analysis leads to organometallic chemistry. As our figuring out of organometallic constitution, houses and mechanisms raises, new methods are opened for the layout of organometallic compounds and reactions adapted to the desires of such diversified components as natural synthesis, clinical examine, biology and fabrics technological know-how. hence the scope of insurance incorporates a large variety of subject matters of natural and utilized organometallic chemistry, the place new breakthroughs are being completed which are of value to a bigger medical viewers. the person volumes of themes in Organometallic Chemistry are thematic. evaluation articles are quite often invited by means of the amount editors. All chapters from themes in Organometallic Chemistry are released OnlineFirst with someone DOI. In references, subject matters in Organometallic Chemistry is abbreviated as best Organomet Chem and pointed out as a journal.

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3 Alkenylation and Amination . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 Conclusions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . T. A. L. T. Carr et al. 1 Introduction Computational chemistry has played a leading role in providing insight into the mechanistic complexity of C–H bond activation.

Chang and Li independently scrutinized the selectivity as well as reactivity of the indoline moiety that is an important structural core in pharmaceutical chemistry (Scheme 16) [99, 100]. G. Kim et al. under mild conditions and the scope of azides was broad including aryl, alkyl, and sulfonyl groups. In addition, a new synthetic route to phosphoramidates was developed using an intermolecular C–H amidation by the action of cationic Cp*Ir (III) catalyst with phosphoryl azides (10). As a result, this carbon–nitrogen bond formation strategy allows a quick access to a library of biologically important compounds [101, 102].

1 Activation of C(sp2)–H Bonds . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Activation of C(sp3)–H Bonds . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 Intermolecular C–H Activation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 C(sp2)–H Activation . . . . . . . . . . . . . . .

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